The title of is "A Gentle Right Arm" . In this episode, Yasutora "Chad" Sado awakens his spiritual powers for the first time while protecting Ichigo's sister, Karin , from a Hollow. Episode Summary
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: Driven by his grandfather's lessons on using his strength only to protect others, Chad’s right arm transforms into a powerful armored form. He uses this new power to destroy the Hollow Bulbous G . The title of is "A Gentle Right Arm"